Stereochemistry Quiz: Test Your Knowledge

Reviewed by Zohra Sattar Waxali
Zohra Sattar Waxali, PhD (Chemistry) |
Chemistry
Review Board Member
Dr. Zohra Sattar Waxali earned her doctorate in chemistry and biochemistry from Northwestern University, specializing in the metallomes of cardiac cells and stem cells, and their impact on biological function. Her research encompasses the development of arsenoplatin chemotherapeutics, stapled peptide estrogen receptor inhibitors, and antimicrobial natural products.
 , PhD (Chemistry)
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  • 1/10 Questions
    Is the molecule shown chiral or achiral? - ProProfs

    Is the molecule shown chiral or achiral?

    • Chiral
    • Achiral
Please wait...
About This Quiz

Stereochemistry, a cornerstone of organic chemistry, explores the intricate spatial arrangements of atoms within molecules and the profound impact these arrangements have on molecular properties and interactions. This Stereochemistry Quiz delves into the fascinating world of three-dimensional molecular structures, challenging your understanding of fundamental stereochemical concepts.

We will learn about the concept of chirality, where molecules exist as non-superimposable mirror images, and delve into the various types of isomers, including enantiomers and diastereomers, which possess unique configurations and exhibit distinct properties. Furthermore, we will examine different methods of visualizing and representing these molecules, such as Fischer projections and Newman projections, to enhance your understanding of their spatial relationships.

Stereochemistry Quiz: Test Your Knowledge - Quiz

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  • 2. 
    Is the molecule shown chiral or achiral? - ProProfs

    Is the molecule shown chiral or achiral?

    • Chiral

    • Achiral

    Correct Answer
    A. Chiral
    Explanation
    This molecule is chiral.Here's why:
    Chiral Center: The central carbon atom is attached to four different groups:

    -CH<sub>2</sub>OH
    -CO<sub>2</sub>H
    -CO<sub>2</sub>H
    -H


    No Plane of Symmetry: You cannot draw any plane through this molecule that would create mirror image halves.
    Important Note: Even though there are two -CO<sub>2</sub>H groups, their spatial arrangement around the central carbon makes them distinct in this 3D structure. This lack of symmetry is what makes the molecule chiral.

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  • 3. 
    Is the molecule shown chiral or achiral? - ProProfs

    Is the molecule shown chiral or achiral?

    • Chiral

    • Achiral

    Correct Answer
    A. Achiral
    Explanation
    The molecule shown is achiral.

     

    Here's why:

     


    Plane of Symmetry: If you draw a plane vertically through the molecule, it divides the structure into two identical halves that are mirror images of each other. This plane of symmetry means the molecule is not chiral.  





     






    Key Concept: A chiral molecule is non-superimposable on its mirror image (like your left and right hands). Achiral molecules are superimposable in their mirror images.



     









     

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  • 4. 
    Is the molecule shown chiral or achiral? - ProProfs

    Is the molecule shown chiral or achiral?

    • Chiral

    • Achiral

    Correct Answer
    A. Achiral
    Explanation
    The molecule shown is achiral. Here's why:Double bond constraint: The molecule has a double bond between two carbon atoms, which restricts rotation around the bond. The two hydrogens attached to the leftmost carbon are identical.Symmetry: For chirality, the carbon at the stereocenter (the carbon attached to four different groups) must have four distinct substituents. In this case, the left side of the molecule has two identical hydrogen atoms attached to the same carbon, making it symmetric.Since the molecule has symmetry and lacks four distinct groups around the potential stereocenter, it is achiral. 

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  • 5. 
    How many asymmetric carbons are present in the compound below? - ProProfs

    How many asymmetric carbons are present in the compound below?

    Correct Answer
    5
    Explanation
    The compound contains five asymmetric carbons. Here's the reasoning:

     

    Definition of an asymmetric carbon: An asymmetric carbon, or chiral carbon, is defined as a carbon atom attached to four distinct groups. To determine the number of asymmetric carbons, one must carefully analyze each carbon in the molecule to check if it connects to four different substituents.

     

    In this compound, all five carbon atoms in the main chain meet this criterion, as each one is attached to four different groups. Hence, the total number of asymmetric carbons is confirmed to be 5.

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  • 6. 
    How many asymmetric carbons are present in the compound below? - ProProfs

    How many asymmetric carbons are present in the compound below?

    • 1

    • 3

    Correct Answer
    A. 1
    Explanation
    There is only one asymmetric carbon in the compound. Here's why:

     

    Definition of an asymmetric carbon: An asymmetric carbon, or chiral carbon, is a carbon atom bonded to four distinct groups, leading to chirality. To identify asymmetric carbons, one must examine each carbon in the structure and determine if it is attached to four different substituents.

     

    Analysis of the compound: In this particular compound, careful examination reveals that only one carbon fulfills this requirement. Therefore, it is classified as the only asymmetric carbon, confirming the answer as 1.

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  • 7. 
    Is the molecule shown chiral or achiral? - ProProfs

    Is the molecule shown chiral or achiral?

    • Chiral

    • Achiral

    Correct Answer
    A. Chiral
    Explanation
    The molecule shown is chiral. Here's why:

     

    Definition of chirality: A chiral molecule cannot be superimposed on its mirror image, meaning it has a unique three-dimensional structure. This distinctiveness arises when a carbon atom is bonded to four different substituents, creating a stereocenter.

     

    Lack of symmetry: In chiral molecules, no plane of symmetry exists that divides the molecule into two identical halves. In this case, the arrangement of the substituents creates an asymmetrical shape, confirming that it is chiral.

     

    Thus, due to the presence of a stereocenter and the absence of symmetry, the molecule is classified as chiral.

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  • 8. 
    Which of the following terms best describes the pair of compounds shown: enantiomers, diastereomers, or the same compound? - ProProfs

    Which of the following terms best describes the pair of compounds shown: enantiomers, diastereomers, or the same compound?

    • Enantiomers

    • Diastereomers

    Correct Answer
    A. Enantiomers
    Explanation
    The pair of compounds shown are enantiomers. Here's why:

     

    Definition of enantiomers: Enantiomers are molecules that are mirror images of each other but cannot be superimposed. They possess the same molecular formula and connectivity but differ in their spatial arrangement around a chiral center.

     

    Superimposition test: When attempting to superimpose one compound over the other, they do not align perfectly due to differences in orientation, confirming that they are enantiomers.

     

    Thus, the compounds are identified as enantiomers because they exhibit this mirror-image relationship and are not superimposable.

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  • 9. 
    How many enantiomers are there of the molecule shown below?   - ProProfs

    How many enantiomers are there of the molecule shown below?  

    • 6

    • 0

    Correct Answer
    A. 0
    Explanation
    There are no enantiomers of the molecule shown. Here's why:

     

    Lack of chiral centers: For a molecule to have enantiomers, it must contain at least one chiral center (a carbon atom bonded to four different groups). In the molecule provided, there are no such asymmetric carbons.

     

    Symmetry: The molecule likely has a plane of symmetry or some form of internal symmetry, which makes it achiral. Symmetrical molecules do not have non-superimposable mirror images.

     

    Since the molecule lacks chiral centers and has symmetry, it does not have any enantiomers, making the correct answer 0.

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  • 10. 
    Which of the following terms best describes the pair of compounds shown: enantiomers, diastereomers, or the same compound? - ProProfs

    Which of the following terms best describes the pair of compounds shown: enantiomers, diastereomers, or the same compound?

    • Enantiomers

    • Diastereomers

    Correct Answer
    A. Enantiomers
    Explanation
    The pair of compounds shown are enantiomers. Here's why:

     

    Non-superimposable mirror images: The two compounds are mirror images of each other, but they cannot be superimposed. This is the defining characteristic of enantiomers.

     

    Stereocenters: Each compound contains one or more stereocenters (chiral carbons), with the spatial arrangement of groups around these centers being opposite in each molecule.

     

    Same connectivity, different spatial arrangement: Both compounds have the same molecular connectivity but differ in the three-dimensional arrangement of their atoms.

     

    Since they are non-superimposable mirror images with chiral centers, the pair of compounds are classified as enantiomers.

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Zohra Sattar Waxali |PhD (Chemistry) |
Chemistry
Dr. Zohra Sattar Waxali earned her doctorate in chemistry and biochemistry from Northwestern University, specializing in the metallomes of cardiac cells and stem cells, and their impact on biological function. Her research encompasses the development of arsenoplatin chemotherapeutics, stapled peptide estrogen receptor inhibitors, and antimicrobial natural products.

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  • Current Version
  • Oct 15, 2024
    Quiz Edited by
    ProProfs Editorial Team

    Expert Reviewed by
    Zohra Sattar Waxali
  • Mar 20, 2011
    Quiz Created by
    Mdrickicki
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