The boiling point of a substance is determined by the strength of its intermolecular forces. Methanol, being an alcohol, has stronger intermolecular forces compared to propane, which is an alkane. Methanol can form hydrogen bonds between its molecules, resulting in stronger attractions. Propane, on the other hand, only has induced dipole-induced dipole forces, which are weaker. Therefore, methanol requires more energy to break the intermolecular forces and transition from a liquid to a gas, resulting in a higher boiling point compared to propane.