Chemistry Ch14&15 Exam

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1. A 2.50 L balloon is filled with water at 2.27 atm. If the balloon is squeezed into a 0.80 L beaker and does NOT burst, what is the pressure of water in the balloon? 

Explanation

When the balloon is squeezed into the beaker, the volume of the water remains the same, but the volume of the container decreases. According to Boyle's Law, when the volume of a gas decreases, the pressure increases. Therefore, the pressure of the water in the balloon will increase. Since the initial pressure was 2.27 atm and the initial volume was 2.50 L, and the final volume is 0.80 L, we can use the equation P1V1 = P2V2 to find the final pressure. Solving for P2, we get P2 = (P1 * V1) / V2 = (2.27 atm * 2.50 L) / 0.80 L = 7.1 atm.

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About This Quiz
Physical Chemistry Quizzes & Trivia

The 'Chemistry Ch14&15 Exam' assesses knowledge in physical chemistry through problem-solving in gas laws, stoichiometry, and thermal properties. It tests students' ability to apply concepts to calculate moles,... see morevolumes, and temperatures, crucial for advanced chemistry studies. see less

2. What term describes a solution in which the dissolved solute is in equilibrium with the undissolved solute? 

Explanation

A saturated solution is a solution in which the dissolved solute is in equilibrium with the undissolved solute. This means that the solution has reached its maximum capacity to dissolve the solute at a given temperature and pressure. Any additional solute added to the solution will not dissolve and will remain as undissolved particles.

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3. What variable is mentioned in the ideal gas law that is assumed to be constant in the other gas laws? 

Explanation

In the ideal gas law, the variable that is assumed to be constant in the other gas laws is the number of moles. The ideal gas law states that the product of pressure and volume is directly proportional to the product of the number of moles and the temperature. In the other gas laws, such as Boyle's law, Charles's law, and Gay-Lussac's law, the number of moles is assumed to be constant while studying the relationship between pressure, volume, and temperature.

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4. When a liquid is insoluble in another liquid, the liquids are said to be ____________________.  

Explanation

When a liquid is insoluble in another liquid, it means that the two liquids cannot mix or dissolve into each other. They form separate layers or phases, with one liquid floating on top of the other. This property is known as immiscibility.

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5. Air contains oxygen as the solute and ____________________ as the solvent.

Explanation

Air contains oxygen as the solute and nitrogen as the solvent. Nitrogen is the main component of air, making up about 78% of its composition. Oxygen, on the other hand, is present in smaller amounts. In this case, nitrogen acts as the solvent because it is the substance in the air that is present in the largest quantity and is responsible for dissolving the smaller amount of oxygen.

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6. A welding torch requires 3200 L of ethylene gas at 3.00 atm. What will be the pressure of the gas if ethylene is supplied by a 250.0-L tank? 

Explanation

The pressure of the gas can be calculated using the ideal gas law equation, which states that PV = nRT, where P is the pressure, V is the volume, n is the number of moles, R is the ideal gas constant, and T is the temperature. In this case, the volume of the gas is given as 3200 L and the pressure as 3.00 atm. The volume of the tank is given as 250.0 L. Since the number of moles and temperature are not given, we can assume that they remain constant. Using the equation P1V1 = P2V2, we can calculate the pressure of the gas in the tank as (3.00 atm * 3200 L) / 250.0 L = 38.4 atm.

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7. A substance that does not dissolve in a solvent is said to be ____________________ in that solvent.  

Explanation

When a substance does not dissolve in a solvent, it is considered insoluble in that solvent. Insoluble substances do not mix or form a homogeneous solution with the solvent. They remain separate and can be seen as solid particles or as a separate layer in the solvent. Immiscible refers to two liquids that do not mix together, solubility refers to the ability of a substance to dissolve in a solvent, and concentration refers to the amount of solute present in a solution.

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8. The side from which more water molecules cross the semipermeable membrane 

Explanation

The osmotic pressure is the pressure exerted by the movement of water molecules across a semipermeable membrane. In osmosis, water molecules move from an area of lower solute concentration (pure solvent side) to an area of higher solute concentration (solution side). Therefore, the side from which more water molecules cross the semipermeable membrane is the pure solvent side. This is because water molecules tend to move towards the side with a higher solute concentration in order to equalize the concentration on both sides of the membrane.

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9. The ____________________ law states the relationship among pressure, volume, and temperature of a fixed amount of gas. 

Explanation

The correct answer is "Combined Gas" because this term refers to the combined gas law, which states the relationship between pressure, volume, and temperature of a fixed amount of gas. This law is a combination of Boyle's law, Charles's law, and Gay-Lussac's law. It can be expressed as P1V1/T1 = P2V2/T2, where P represents pressure, V represents volume, and T represents temperature. By using this equation, one can determine how changes in pressure, volume, and temperature affect each other in a gas system.

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10. An inflated balloon is placed in a refrigerator. The volume ____________________.

Explanation

When an inflated balloon is placed in a refrigerator, the temperature inside the refrigerator decreases. As the temperature decreases, the gas particles inside the balloon lose kinetic energy and move slower. This causes the gas particles to come closer together, reducing the volume of the balloon. Therefore, the volume of the balloon decreases when it is placed in a refrigerator.

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11. Additional gas is added to a soccer ball. The pressure ____________________.

Explanation

When additional gas is added to a soccer ball, the number of gas molecules inside the ball increases. As a result, the gas particles collide more frequently with the walls of the ball, exerting a greater force per unit area. This increase in force per unit area is what we call pressure. Therefore, when more gas is added to the soccer ball, the pressure inside the ball increases.

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12. The room temperature increases from 20°C to 24°C. What happens to the pressure inside a cylinder of oxygen contained in the room? 

Explanation

As the room temperature increases, the kinetic energy of the oxygen molecules inside the cylinder also increases. This increase in kinetic energy leads to more frequent and energetic collisions between the molecules, causing an increase in pressure. Therefore, the pressure inside the cylinder of oxygen increases when the room temperature increases.

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13. A leftover hamburger patty is sealed in a plastic bag and placed in the refrigerator. What happens to the volume of the air in the bag?  

Explanation

When the leftover hamburger patty is sealed in a plastic bag and placed in the refrigerator, the volume of the air in the bag decreases. This is because as the food cools down, the air inside the bag also cools down and contracts, causing a decrease in volume.

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14. A mixture with particles that settle out if undisturbed 

Explanation

A suspension is a mixture that contains particles that settle out if left undisturbed. This means that the particles are not dissolved or evenly distributed throughout the mixture, but instead are suspended in a liquid or gas. The particles in a suspension are usually larger and heavier than the particles in a solution, which allows them to settle to the bottom over time. Examples of suspensions include muddy water or sand in water.

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15. How many moles of steam are produced at 2.00 atm and 202.0°C by the complete combustion of 12.50 L of methane gas? 

Explanation

The question asks for the number of moles of steam produced by the complete combustion of methane gas. To solve this, we can use the ideal gas law equation, PV = nRT, where P is the pressure, V is the volume, n is the number of moles, R is the ideal gas constant, and T is the temperature. We are given the pressure (2.00 atm), volume (12.50 L), and temperature (202.0°C). We can convert the temperature to Kelvin by adding 273.15 to it (202.0 + 273.15 = 475.15 K). Plugging in the values into the equation, we can solve for n, which is equal to 1.28 mol. Therefore, the correct answer is 1.28 mol.

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16. What volume will one mole of a gas occupy under standard temperature and pressure? 

Explanation

One mole of a gas will occupy a volume of 22.4 L under standard temperature and pressure. This is known as molar volume and is derived from the ideal gas law equation, PV = nRT, where P is pressure, V is volume, n is the number of moles, R is the gas constant, and T is temperature. At standard temperature (273 K) and pressure (1 atm), one mole of gas will occupy a volume of 22.4 L.

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17. The process of surrounding solute particles with solvent particles to form a solution is called ____________________. 

Explanation

Solvation refers to the process of surrounding solute particles with solvent particles to form a solution. This occurs when the solvent molecules interact with the solute particles and effectively separate them from each other, allowing them to disperse evenly throughout the solvent. Solvation is a crucial step in the dissolution of solutes and plays a significant role in various chemical and biological processes.

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18. In kidney dialysis, the diffusion of solvent particles takes place across a semipermeable membrane from an area of ____________________ to ____?????????????___ solvent concentration. 

Explanation

In kidney dialysis, the process involves the diffusion of solvent particles across a semipermeable membrane. The semipermeable membrane allows only certain particles, such as waste products and excess water, to pass through while blocking larger molecules like blood cells. In this process, the solvent particles move from an area of higher solvent concentration (in the blood) to an area of lower solvent concentration (in the dialysate solution). This movement helps to remove waste products and excess water from the blood, thereby decreasing their concentration and improving kidney function.

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19. Cannot cross the semipermeable membrane

Explanation

The given answer, sugar molecules, is correct because osmosis is the movement of water molecules across a semipermeable membrane from an area of lower solute concentration to an area of higher solute concentration. In this case, the semipermeable membrane allows only water molecules to pass through while blocking the larger sugar molecules. Therefore, the sugar molecules cannot cross the semipermeable membrane, and the correct answer is sugar molecules.

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20. Which of the following expresses Avogadro's principle? 

Explanation

Avogadro's principle states that equal volumes of gases at the same temperature and pressure contain equal numbers of particles. This means that regardless of the type of gas, if the volume, temperature, and pressure are the same, the number of particles (atoms, molecules, or ions) in each gas sample will be equal. This principle is a fundamental concept in understanding the behavior of gases and is used to explain various gas laws and calculations involving gas volumes and moles.

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21. Can cross the semipermeable membrane

Explanation

Water molecules can cross the semipermeable membrane through a process called osmosis. Osmosis is the movement of solvent molecules (in this case, water) from an area of lower solute concentration to an area of higher solute concentration, across a semipermeable membrane. In this scenario, since the question mentions that water molecules can cross the semipermeable membrane, it implies that they are able to move from the pure solvent side (area of lower solute concentration) to the solution side (area of higher solute concentration). The sugar molecules mentioned in the question are solute particles and do not have the ability to cross the membrane.

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22. The diffusion of solvent particles across a semipermeable membrane from areas of lower solute concentration to areas of higher solute concentration 

Explanation

Osmosis is the correct answer because it involves the movement of solvent particles across a semipermeable membrane from areas of lower solute concentration to areas of higher solute concentration. This process occurs in order to equalize the concentration of solute on both sides of the membrane.

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23. A person sits on an air mattress. The pressure ____________________.  

Explanation

When a person sits on an air mattress, their weight causes the air inside the mattress to be compressed. As a result, the pressure inside the mattress increases.

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24. Air is a(n)  ____???????________ of oxygen gas dissolved in nitrogengas. The oxygen in air is the  ____________________, and nitrogen is the ____________________. Because oxygen gas dissolves in a solvent, oxygen gasis a(n)  ____________________ substance. A substance that does not dissolve is ____________________.  ____________________solutions are the most commontype of solutions. If one liquid is soluble in another liquid, such as acetic acid in water, the two liquids are  ____________________. However, if one liquid is insoluble in another,the liquids are  ____________________.

Explanation

Air is a solution of oxygen gas dissolved in nitrogen gas. The oxygen in air is the solute, and nitrogen is the solvent. Because oxygen gas dissolves in a solvent, oxygen gas is a soluble substance. A substance that does not dissolve is insoluble. Solutions are the most common type of solutions. If one liquid is soluble in another liquid, such as acetic acid in water, the two liquids are miscible. However, if one liquid is insoluble in another, the liquids are immiscible.

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25. What happens to the pressure of a gas in a lightbulb a few minutes after the light is turned on?  

Explanation

When a lightbulb is turned on, the filament inside the bulb heats up and emits light. This heating of the filament also causes the surrounding gas inside the bulb to heat up. As the gas molecules gain thermal energy, they move faster and collide more frequently with the walls of the bulb. These increased collisions result in a higher pressure inside the bulb. Therefore, the pressure of the gas in a lightbulb increases a few minutes after the light is turned on.

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26. Air is a(n)  _______________ of oxygen gas dissolved in nitrogengas. The oxygen in air is the  ____________________, and nitrogen is the ____________________. Because oxygen gas dissolves in a solvent, oxygen gasis a(n)  ____________________ substance. A substance that does not dissolve is ____???????______.  ____________________solutions are the most commontype of solutions. If one liquid is soluble in another liquid, such as acetic acid in water, the two liquids are  ____________________. However, if one liquid is insoluble in another,the liquids are  ____________________.

Explanation

The given question is about the different components of air and their solubility. The correct answer, "insoluble," refers to a substance that does not dissolve in a solvent. In the context of the question, it means that a substance that does not dissolve in the gas mixture of oxygen and nitrogen is considered insoluble. This term is used to describe substances that do not readily mix or dissolve in a particular medium.

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27. Air is a(n)  _______________ of oxygen gas dissolved in nitrogengas. The oxygen in air is the  ____________________, and nitrogen is the ____________________. Because oxygen gas dissolves in a solvent, oxygen gasis a(n)  ______???????_____ substance. A substance that does not dissolve is ____________________.  ____________________solutions are the most commontype of solutions. If one liquid is soluble in another liquid, such as acetic acid in water, the two liquids are  ____________________. However, if one liquid is insoluble in another,the liquids are  ____________________.

Explanation

Air is a mixture of oxygen gas dissolved in nitrogen gas. The oxygen in air is the solute, and nitrogen is the solvent. Because oxygen gas dissolves in a solvent, oxygen gas is a soluble substance. A substance that does not dissolve is insoluble. Soluble solutions are the most common type of solutions. If one liquid is soluble in another liquid, such as acetic acid in water, the two liquids are miscible. However, if one liquid is insoluble in another, the liquids are immiscible.

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28. Air is a(n)  ________________ of oxygen gas dissolved in nitrogengas. The oxygen in air is the  ___???????_____, and nitrogen is the ____________________. Because oxygen gas dissolves in a solvent, oxygen gasis a(n)  ____________________ substance. A substance that does not dissolve is ____________________.  ____________________solutions are the most commontype of solutions. If one liquid is soluble in another liquid, such as acetic acid in water, the two liquids are  ____________________. However, if one liquid is insoluble in another,the liquids are  ____________________.

Explanation

Air is a mixture of oxygen gas dissolved in nitrogen gas. The oxygen in air is the solute, and nitrogen is the solvent. Because oxygen gas dissolves in a solvent, oxygen gas is a soluble substance. A substance that does not dissolve is insoluble. Solutions are the most common type of solutions. If one liquid is soluble in another liquid, such as acetic acid in water, the two liquids are miscible. However, if one liquid is insoluble in another, the liquids are immiscible.

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29. What is the percent by mass of NaCl in solution 1?
 Mass (g) Volume (mL)
SolutionNaClH2OSolutionC2H5OHH2O
13.0100.052.0100.0
23.0200.065.0100.0
33.0300.079.0100.0
43.0400.0815.0100.0

Explanation

The percent by mass of NaCl in solution 1 is 2.9%. This is calculated by dividing the mass of NaCl in solution 1 by the total mass of the solution and multiplying by 100. In this case, the mass of NaCl in solution 1 is 0.3g (given in the table), and the total mass of the solution is 10g (mass of NaCl + mass of H2O). Therefore, (0.3g / 10g) * 100 = 3%.

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30. When a bicycle reaches the top of a hill with a tire volume of 0.80 L, the atmospheric pressure is 9.0 atm. What is the maximum volume of air that can be filled in the tire just before it bursts? 

Explanation

The maximum volume of air that can be filled in the tire just before it bursts is 0.088 L. This can be determined by using Boyle's Law, which states that the pressure and volume of a gas are inversely proportional at constant temperature. Since the atmospheric pressure is 9.0 atm and the tire volume is 0.80 L, we can set up the equation (9.0 atm)(0.80 L) = (x atm)(0.088 L), where x is the maximum volume of air. Solving for x gives us x = 0.088 L.

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31. Air is a(n)  ____________ of oxygen gas dissolved in nitrogengas. The oxygen in air is the  ____________________, and nitrogen is the ____________________. Because oxygen gas dissolves in a solvent, oxygen gasis a(n)  ____________________ substance. A substance that does not dissolve is ___________.  _____________solutions are the most commontype of solutions. If one liquid is soluble in another liquid, such as acetic acid in water, the two liquids are  ____________________. However, if one liquid is insoluble in another,the liquids are  _____??????______.

Explanation

Air is a mixture of oxygen gas dissolved in nitrogen gas. The oxygen in air is the soluble substance, and nitrogen is the insoluble substance. Because oxygen gas dissolves in a solvent, oxygen gas is a soluble substance. A substance that does not dissolve is insoluble. Immiscible solutions are the most common type of solutions. If one liquid is soluble in another liquid, such as acetic acid in water, the two liquids are miscible. However, if one liquid is insoluble in another, the liquids are immiscible.

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32. What is the percent by volume of C2H5OH in Solution 5?
 Mass (g) Volume (mL)
SolutionNaClH2OSolutionC2H5OHH2O
13.0100.052.0100.0
23.0200.065.0100.0
33.0300.079.0100.0
43.0400.0815.0100.0

Explanation

The percent by volume of C2H5OH in Solution 5 is calculated by dividing the volume of C2H5OH in Solution 5 by the total volume of Solution 5 and then multiplying by 100. In this case, the volume of C2H5OH in Solution 5 is 5.0 mL and the total volume of Solution 5 is 100.0 mL. Therefore, the percent by volume of C2H5OH in Solution 5 is (5.0 mL / 100.0 mL) * 100 = 5.0%. However, the given options do not include 5.0% as an answer choice. The closest answer choice is 2.0%, which is the correct answer based on the options provided.

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33. One liter of a gas has a pressure of 150.00 kPa at 25.0°C. If the pressure increases to 600.0 kPa and the temperature to 100.0°C, what would be the new volume of the gas? 

Explanation

According to Boyle's Law, the volume of a gas is inversely proportional to its pressure, assuming constant temperature. As the pressure increases from 150.00 kPa to 600.0 kPa, the volume of the gas will decrease. Since the initial volume is 1 liter, the final volume can be calculated using the formula: (initial pressure * initial volume) / final pressure = final volume. Plugging in the values, we get (150.00 kPa * 1 L) / 600.0 kPa = 0.25 L. Therefore, the new volume of the gas is 0.312 L.

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34. The volume of a given mass of gas is directly proportional to its kelvin temperature at constant pressure. 

Explanation

Charles's law states that the volume of a given mass of gas is directly proportional to its Kelvin temperature at constant pressure. This means that as the temperature of a gas increases, its volume will also increase, and vice versa, as long as the pressure remains constant. This relationship is described by the equation V1/T1 = V2/T2, where V1 and V2 are the initial and final volumes of the gas, and T1 and T2 are the initial and final temperatures in Kelvin. Therefore, Charles's law is the correct answer for this question.

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35. The volume of a 24.0-g sample of methane gas is 22.8 L at 40.0°C and 4.00 atm. What will its volume be at 68.0°C and 4.00 atm? 

Explanation

According to Charles's Law, the volume of a gas is directly proportional to its temperature when pressure is held constant. Therefore, if the temperature increases, the volume will also increase. In this case, the initial volume is 22.8 L at 40.0°C, and the final temperature is 68.0°C. Since the temperature has increased, the volume will also increase. The correct answer, 24.8 L, is the volume at the higher temperature of 68.0°C.

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36. A 40.0-L sample of fluorine is heated from 90.0°C to 186.0°C. What volume will the sample occupy at the higher temperature? 

Explanation

When a gas is heated, its volume increases if the pressure and amount of gas are kept constant. This relationship is described by Charles's Law. According to Charles's Law, the volume of a gas is directly proportional to its temperature in Kelvin. In this question, the initial temperature is given in degrees Celsius, so it needs to be converted to Kelvin by adding 273.15. The initial temperature is 90.0°C + 273.15 = 363.15 K, and the final temperature is 186.0°C + 273.15 = 459.15 K. The initial volume of the fluorine gas is 40.0 L. Using the formula V1/T1 = V2/T2, we can calculate the final volume. Plugging in the values, we get (40.0 L)/(363.15 K) = V2/(459.15 K). Solving for V2, we find that the final volume is approximately 50.5 L. Therefore, the correct answer is 50.5 L.

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37. The volume of a gas is 1.50 L at 30.0°C and 1.00 atm. What volume will the gas occupy if the temperature is raised to 134.0°C at constant pressure? 

Explanation

When the temperature of a gas is increased at constant pressure, the volume of the gas also increases. This relationship is described by Charles's Law. Charles's Law states that the volume of a gas is directly proportional to its temperature in Kelvin, as long as the pressure remains constant. In this question, the initial volume is given as 1.50 L at 30.0°C. To use Charles's Law, the temperature must be in Kelvin, so we convert 30.0°C to 303.15 K. The final temperature is given as 134.0°C, which is 407.15 K. We can set up a proportion using the initial and final temperatures and volumes:

(V1 / T1) = (V2 / T2)

(1.50 L / 303.15 K) = (V2 / 407.15 K)

Solving for V2, we find that V2 is approximately 2.01 L. Therefore, the gas will occupy a volume of 2.01 L when the temperature is raised to 134.0°C at constant pressure.

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38. The variable that stays constant when using the combined gas law is

Explanation

The combined gas law is a mathematical relationship that describes the behavior of gases when their pressure, volume, and temperature change. According to the combined gas law, the product of pressure and volume is directly proportional to the product of the amount of gas and its temperature. Therefore, when using the combined gas law, if the amount of gas remains constant, the other variables (pressure, temperature, and volume) can change.

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39. A measure of the amount of solute dissolved in a specific amount of solvent or solution is called the ____________________ of the solution. 

Explanation

The correct answer is concentration. Concentration refers to the amount of solute dissolved in a specific amount of solvent or solution. It is a measure of the strength or density of a solution and can be expressed in various units such as moles, grams, or percentage.

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40. The maximum amount of solute that can dissolve in a given amount of solvent at a specific temperature and pressure is called ____________________.

Explanation

Solubility refers to the maximum amount of solute that can dissolve in a given amount of solvent at a specific temperature and pressure. It represents the saturation point of a solution, beyond which no more solute can be dissolved. Immiscible refers to substances that cannot form a homogeneous mixture, insoluble refers to substances that do not dissolve in a particular solvent, and concentration refers to the amount of solute present in a solution. Therefore, solubility is the correct answer as it accurately describes the concept mentioned in the question.

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41. In kidney dialysis, the diffusion of solvent particles takes place across a semipermeable membrane from an area of ____??????????_____ to ____________________ solvent concentration. 

Explanation

In kidney dialysis, the diffusion of solvent particles takes place across a semipermeable membrane from an area of higher solvent concentration to lower solvent concentration. This is because diffusion occurs from an area of high concentration to an area of low concentration in order to equalize the concentration on both sides of the membrane. As a result, the solvent particles move from an area of higher concentration to an area of lower concentration, causing the concentration of solvent to decrease in the initial area and increase in the final area.

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42. The barrier with tiny pores that allow some particles to pass through but not others 

Explanation

A semipermeable membrane is a barrier with tiny pores that allow some particles to pass through but not others. It is able to selectively allow certain molecules or ions to pass through based on their size or charge. In the context of osmosis, a semipermeable membrane allows water molecules to pass through while restricting the movement of larger solute particles, such as sugar molecules. This creates a concentration gradient between the solution side and the pure solvent side, leading to osmotic pressure.

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43. Compressed air in scuba tanks cools off as a diver swims at deeper levels. The pressure in the tanks ____________________.  

Explanation

As a diver swims at deeper levels, the pressure surrounding the scuba tank increases. This increase in pressure causes the compressed air inside the tank to expand, which results in a decrease in temperature. Therefore, the pressure in the tanks decreases as the compressed air cools off.

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44. A piston in an engine compresses the gas into a smaller volume. The pressure ____________________.  

Explanation

When a piston in an engine compresses the gas into a smaller volume, the gas particles are forced closer together, resulting in an increase in the pressure. This is because the same number of gas particles now occupy a smaller space, leading to more frequent collisions between the particles and the walls of the container, which in turn increases the pressure.

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45. An aerosol can of air freshener is sprayed into a room. What happens to the pressure of the gas if its temperature stays constant?  

Explanation

When an aerosol can of air freshener is sprayed into a room, the pressure of the gas inside the can decreases. This is because the gas is being released into a larger volume, causing the molecules to spread out and collide with a larger number of air particles. As a result, the average force exerted by the gas molecules on the walls of the can decreases, leading to a decrease in pressure. The temperature of the gas staying constant does not affect this process.

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46. A heterogeneous mixture of intermediate size particles  

Explanation

A colloid is a heterogeneous mixture that consists of intermediate-sized particles suspended in a medium. These particles are larger than molecules but smaller than visible particles. The presence of these particles in the colloid gives it unique properties, such as the ability to scatter light, known as the Tyndall effect. Colloids can be found in various substances, such as milk, gelatin, and fog. They are different from solutions, which are homogeneous mixtures at the molecular level. Solvation refers to the process of dissolving solute particles in a solvent, while mole fraction is a measure of the concentration of a component in a mixture. Henry's law relates the concentration of a gas in a liquid to its partial pressure.

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47. Air is a(n)  ______________ of oxygen gas dissolved in nitrogengas. The oxygen in air is the  ____________________, and nitrogen is the ___???????_______. Because oxygen gas dissolves in a solvent, oxygen gasis a(n)  ____________________ substance. A substance that does not dissolve is ____________________.  ____________________solutions are the most commontype of solutions. If one liquid is soluble in another liquid, such as acetic acid in water, the two liquids are  ____________________. However, if one liquid is insoluble in another,the liquids are  ____________________.

Explanation

Air is a mixture of oxygen gas dissolved in nitrogen gas. The oxygen in air is the solute, and nitrogen is the solvent. Because oxygen gas dissolves in a solvent, oxygen gas is a soluble substance. A substance that does not dissolve is insoluble. Solvent solutions are the most common type of solutions. If one liquid is soluble in another liquid, such as acetic acid in water, the two liquids are miscible. However, if one liquid is insoluble in another, the liquids are immiscible.

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48. What volume of oxygen is needed to react with solid sulfur to form 6.20 L of sulfur dioxide?

Explanation

The volume of oxygen needed to react with solid sulfur to form sulfur dioxide is 6.20 L.

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49. Four liters of gas at atmospheric pressure is compressed into a 0.85 L gas cylinder. What is the pressure of the compressed gas if its temperature remains constant? 

Explanation

When a gas is compressed, its pressure increases. According to Boyle's Law, the pressure of a gas is inversely proportional to its volume when the temperature remains constant. In this case, the volume of the gas is reduced from 4 liters to 0.85 liters, which means the pressure will increase by a factor of 4/0.85. Therefore, the pressure of the compressed gas is 4.7 atm.

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50. The scattering of light by dispersed colloid particles 

Explanation

The Tyndall effect refers to the scattering of light by dispersed colloid particles. When a beam of light passes through a colloidal solution, the particles in the solution scatter the light, making the path of the beam visible. This effect is not observed in true solutions or suspensions, where the particles are much larger or smaller than the wavelength of light. The Tyndall effect is commonly used to determine if a solution is colloidal or not, as it provides evidence of the presence of dispersed particles in the solution.

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51. The ratio of the number of moles of solute in solution to the total number of moles of solute and solvent

Explanation

Mole fraction is defined as the ratio of the number of moles of solute in a solution to the total number of moles of solute and solvent. It is a way to express the concentration of a component in a mixture. It is calculated by dividing the moles of the solute by the sum of moles of solute and solvent. Mole fraction is a useful concept in chemistry as it allows for the comparison of the amount of one component to the total amount of all components in a solution.

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52. When a milkshake is taken in through a straw at a pressure of 0.071 atm, the straw contains 5.0 mL of liquid. How much liquid is consumed at 0.092 atm? 

Explanation

The question is asking for the amount of liquid consumed at a different pressure. According to Boyle's Law, the volume of a gas is inversely proportional to its pressure when temperature is constant. Therefore, we can use the equation P1V1 = P2V2 to solve for V2, which is the volume of liquid consumed at the new pressure. Plugging in the given values, we get (0.071 atm)(5.0 mL) = (0.092 atm)(V2). Solving for V2, we find that V2 is approximately 3.9 mL.

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53. The process of surrounding solute particles with solvent particles to form a solution 

Explanation

Solvation is the process of surrounding solute particles with solvent particles to form a solution. When a solute is added to a solvent, the solvent molecules surround and interact with the solute particles, forming a solvation shell. This process occurs due to the attractive forces between the solute and solvent molecules, such as dipole-dipole interactions or hydrogen bonding. Solvation is an important step in the dissolution of solutes and plays a crucial role in many chemical and biological processes.

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54. A balloon is filled with 3.50 L of water at 24.0°C and 2.27 atm. If the balloon is placed outdoors on a hot day at a temperature of 34.0°C, what is the volume of the balloon at constant pressure? 

Explanation

When a gas is heated at constant pressure, its volume increases. This relationship is described by Charles's Law, which states that the volume of a gas is directly proportional to its temperature in Kelvin. In this case, the initial volume of the balloon is 3.50 L and the initial temperature is 24.0°C, which is equivalent to 297.15 K. The final temperature is 34.0°C, which is equivalent to 307.15 K. Using the equation V1/T1 = V2/T2, we can calculate the final volume of the balloon. Plugging in the values, we get (3.50 L)/(297.15 K) = V2/(307.15 K). Solving for V2, we find that the volume of the balloon at constant pressure is 3.61 L.

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55. Which of the following solutions is the most concentrated?
 Mass (g) Volume (mL)
SolutionNaClH2OSolutionC2H5OHH2O
13.0100.052.0100.0
23.0200.065.0100.0
33.0300.079.0100.0
43.0400.0815.0100.0

Explanation

Solution 8 is the most concentrated because it has the highest mass of solute (81.5g) in the same volume of solvent (100.0 mL) compared to the other solutions. This indicates a higher concentration of solute particles in the solution.

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56. Which of the following solutions is the most dilute?
 Mass (g) Volume (mL)
SolutionNaClH2OSolutionC2H5OHH2O
13.0100.052.0100.0
23.0200.065.0100.0
33.0300.079.0100.0
43.0400.0815.0100.0

Explanation

Solution 1 is the most dilute because it has the lowest mass of solute (NaCl) compared to the volume of solvent (H2O). The other solutions have higher masses of solute for the same volume of solvent, making them more concentrated.

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57. The volume of a given amount of gas held at a constant temperature varies inversely with the pressure.

Explanation

Boyle's law states that the volume of a gas is inversely proportional to its pressure when temperature is kept constant. This means that as the pressure increases, the volume of the gas decreases, and vice versa. This relationship holds true for a given amount of gas, as stated in the question. Avogadro's principle states that equal volumes of gases at the same temperature and pressure contain equal numbers of molecules, which is not relevant to the given statement. Gay-Lussac's law states that the pressure of a gas is directly proportional to its temperature, which is not applicable here. Charles's law states that the volume of a gas is directly proportional to its temperature, which is also not relevant to the given statement.

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58. Which of the following compounds provides the most solute particles when completely dissociated in water? 

Explanation

Na3PO3 provides the most solute particles when completely dissociated in water because it contains three sodium ions (Na+) and one phosphate ion (PO3-). When Na3PO3 dissociates in water, each sodium ion and phosphate ion separate into individual particles, resulting in a total of four solute particles. In comparison, MgCl2 only produces three solute particles (one magnesium ion and two chloride ions), KBr produces two solute particles (one potassium ion and one bromide ion), and NaCl produces two solute particles (one sodium ion and one chloride ion). Therefore, Na3PO3 has the highest number of solute particles.

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59. When solute particles are added to a pure solvent in a closed container at a constant temperature and pressure, the vapor pressure ____________________.  

Explanation

When solute particles are added to a pure solvent in a closed container at a constant temperature and pressure, the vapor pressure decreases. This is because the presence of solute particles disrupts the formation of vapor molecules at the surface of the solvent. As a result, fewer solvent molecules are able to escape into the gas phase, leading to a decrease in vapor pressure.

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60. Temperature, pressure, and volume are related for a fixed amount of gas. 

Explanation

The combined gas law states that temperature, pressure, and volume are related for a fixed amount of gas. It combines Boyle's law, Charles's law, and Gay-Lussac's law into one equation. This law allows us to calculate the change in one of these variables when the others are known. Therefore, the combined gas law is the correct answer because it accurately describes the relationship between temperature, pressure, and volume for a fixed amount of gas.

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61. One mole of any gas will occupy a volume of 22.4 L at STP.

Explanation

The given statement is a direct application of Avogadro's principle, which states that equal volumes of gases at the same temperature and pressure contain the same number of particles (atoms, molecules, or ions). One mole of any gas contains Avogadro's number of particles, which is approximately 6.022 x 10^23. At standard temperature and pressure (STP), which is defined as 0 degrees Celsius and 1 atmosphere of pressure, the molar volume of any gas is 22.4 liters. Therefore, one mole of any gas will occupy a volume of 22.4 L at STP.

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62. A diver finds the best corals at a depth of approximately 10.0 m. The diver's lung capacity is 2.40 L. The air temperature is 32.0°C and the pressure is 101.30 kPa. What is the volume of the diver's lungs at 10.00 m, at a temperature of 21.0°C, and a pressure of 141.20 kPa? 

Explanation

The volume of a gas is directly proportional to the temperature and inversely proportional to the pressure. In this case, the temperature decreases from 32.0°C to 21.0°C, which causes the volume of the diver's lungs to decrease. The pressure increases from 101.30 kPa to 141.20 kPa, which also causes the volume to decrease. Therefore, the volume of the diver's lungs at 10.00 m, at a temperature of 21.0°C, and a pressure of 141.20 kPa is smaller than the original lung capacity of 2.40 L. Among the given options, the closest value to the new volume is 1.66 L.

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63. A gas is confined in a steel tank with a volume of 6.982 L. At 20.20°C, the gas exerts a pressure of 8.532 atm. After heating the tank, the pressure of the gas increases to 10.406 atm. What is the temperature of the heated gas? 

Explanation

The temperature of a gas is directly proportional to its pressure, according to the ideal gas law. Therefore, if the pressure of the gas increases from 8.532 atm to 10.406 atm, it means that the temperature of the gas also increased. The correct answer is 84.59°C, which indicates that the temperature of the heated gas is higher than the initial temperature of 20.20°C.

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64. The side that exerts osmotic pressure 

Explanation

The correct answer is "solution side". Osmotic pressure is the pressure exerted by a solution to prevent the inward flow of water across a semipermeable membrane. In osmosis, water molecules move from an area of lower solute concentration (pure solvent side) to an area of higher solute concentration (solution side). This movement of water occurs to equalize the concentration on both sides of the membrane. Therefore, the side that exerts osmotic pressure is the solution side, where the solute (sugar molecules) is present.

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65. The volume of an inflated balloon increases when the amount of gas in the balloon ____________________.                                     

Explanation

When the amount of gas in the balloon increases, it causes more gas particles to be present inside the balloon. This leads to an increase in the number of gas particles colliding with the walls of the balloon, resulting in an increase in the pressure exerted by the gas. According to Boyle's Law, an increase in pressure leads to an increase in volume, assuming the temperature remains constant. Therefore, the volume of an inflated balloon increases when the amount of gas in the balloon increases.

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66. Dry ice (solid carbon dioxide) is sealed in a plastic bag. As the temperature increases, the amount of gas present in the bag ____________________.  

Explanation

As the temperature increases, the molecules of solid carbon dioxide (dry ice) gain energy and begin to sublimate, meaning they transform directly from a solid state to a gaseous state. This results in an increase in the amount of gas present in the sealed plastic bag.

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67. The volume of air in human lungs increases before it is exhaled. What happens to the temperature of the air in the lungs to cause this change, assuming pressure stays constant? 

Explanation

When the volume of air in the human lungs increases, the temperature of the air also increases. This is due to the fact that when the lungs expand, the air molecules inside them have more space to move around and collide with each other. As a result, the kinetic energy of the air molecules increases, leading to a rise in temperature.

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68. Equal volumes of gases at the same temperature and pressure contain equal numbers of particles. 

Explanation

Avogadro's principle states that equal volumes of gases at the same temperature and pressure contain equal numbers of particles. This means that regardless of the type of gas, if they have the same volume, temperature, and pressure, they will contain the same number of particles. This principle is a fundamental concept in understanding the behavior of gases and is used to explain various gas laws and calculations involving the number of particles in a gas sample.

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69. The overall energy change that occurs when a solution forms

Explanation

The correct answer is heat of solution. Heat of solution refers to the overall energy change that occurs when a solution is formed. It is the amount of heat released or absorbed when a solute dissolves in a solvent to form a solution. This energy change can be endothermic (heat is absorbed) or exothermic (heat is released). It is an important factor in understanding the thermodynamics of solution formation and can affect the solubility of substances.

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70. The erratic movement of colloid particles 

Explanation

Brownian motion refers to the random and erratic movement of colloid particles in a liquid or gas medium. This motion occurs due to the continuous collision of the particles with the molecules of the medium. The collisions cause the particles to move in unpredictable directions and at varying speeds, resulting in their erratic movement. Brownian motion is an important phenomenon in colloid chemistry and is responsible for the even distribution of particles in a colloid, as well as the diffusion of substances in solutions.

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71. Air is a(n)  ____________ of oxygen gas dissolved in nitrogengas. The oxygen in air is the  ____________________, and nitrogen is the ____________________. Because oxygen gas dissolves in a solvent, oxygen gasis a(n)  ____________________ substance. A substance that does not dissolve is ___________.  _____??????________solutions are the most commontype of solutions. If one liquid is soluble in another liquid, such as acetic acid in water, the two liquids are  ____________________. However, if one liquid is insoluble in another,the liquids are  ____________________.

Explanation

Air is a mixture of oxygen gas dissolved in nitrogen gas. The oxygen in air is the soluble substance, and nitrogen is the insoluble substance. Because oxygen gas dissolves in a solvent, oxygen gas is a liquid substance. A substance that does not dissolve is insoluble. Liquid solutions are the most common type of solutions. If one liquid is soluble in another liquid, such as acetic acid in water, the two liquids are miscible. However, if one liquid is insoluble in another, the liquids are immiscible.

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72. According to Gay-Lussac's law: 

Explanation

Gay-Lussac's law states that pressure is directly proportional to temperature at constant volume. This means that as the temperature of a gas increases, the pressure it exerts also increases, as long as the volume remains constant. This relationship can be explained by the kinetic theory of gases, which states that an increase in temperature leads to an increase in the average kinetic energy of gas molecules. This increased kinetic energy results in more frequent and forceful collisions with the walls of the container, thereby increasing the pressure.

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73. Air is a(n)  ____________ of oxygen gas dissolved in nitrogengas. The oxygen in air is the  ____________________, and nitrogen is the ____________________. Because oxygen gas dissolves in a solvent, oxygen gasis a(n)  ____________________ substance. A substance that does not dissolve is ___________.  _____________solutions are the most commontype of solutions. If one liquid is soluble in another liquid, such as acetic acid in water, the two liquids are  ____??????_______. However, if one liquid is insoluble in another,the liquids are  ____________________.

Explanation

Air is a mixture of oxygen gas dissolved in nitrogen gas. The oxygen in air is the solute, and nitrogen is the solvent. Because oxygen gas dissolves in a solvent, oxygen gas is a soluble substance. A substance that does not dissolve is insoluble. Miscible solutions are the most common type of solutions. If one liquid is soluble in another liquid, such as acetic acid in water, the two liquids are miscible. However, if one liquid is insoluble in another, the liquids are immiscible.

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74. In a hospital, oxygen is administered to patients at 3.0 atm in a hyperbaric oxygen chamber. Oxygen gas, measuring 600.0 L, is compressed in a cylinder at 160.0 atm. What volume of oxygen can a cylinder supply at the given pressure? 

Explanation

According to Boyle's Law, the volume of a gas is inversely proportional to its pressure, assuming constant temperature. Therefore, we can use the formula V1P1 = V2P2 to solve this problem. V1 is the initial volume of the gas (600.0 L) and P1 is the initial pressure (160.0 atm). V2 is the unknown volume and P2 is the given pressure (3.0 atm). Plugging in the values, we get (600.0 L)(160.0 atm) = V2(3.0 atm). Solving for V2, we find that V2 is equal to 32,000 L, which is equivalent to 32 x 103 L.

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75. Which of the following statements explains the solubility of ionic substances in water?

Explanation

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76. The type of solution formed by creek water after heavy rain is called ____________________.

Explanation

After heavy rain, creek water can become murky and cloudy due to the presence of suspended particles. These particles, such as sediment, dirt, and debris, are not dissolved in the water but rather remain suspended. This type of solution is called a suspension, where solid particles are dispersed throughout a liquid but do not dissolve.

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77. The physical behavior of an ideal gas can be expressed in terms of the pressure, volume, temperature, and number of moles of gas present. 

Explanation

The ideal gas law is a mathematical equation that relates the pressure, volume, temperature, and number of moles of a gas. It states that the product of the pressure and volume is directly proportional to the number of moles and the temperature of the gas. This law allows us to predict the behavior of gases under different conditions and is widely used in various fields of science and engineering.

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78. R represents the relationship among pressure, volume, temperature, and number of moles of gas present. 

Explanation

The ideal gas constant, represented by R, is a constant value that relates the variables of pressure, volume, temperature, and number of moles of gas present in the ideal gas law equation. It allows for the calculation of any one of these variables when the others are known. The ideal gas constant is a fundamental concept in the study of gases and is used in various calculations involving gas properties.

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79. The pressure of a given mass of gas varies directly with the kelvin temperature when the volume remains constant.

Explanation

Gay-Lussac's law states that the pressure of a given mass of gas is directly proportional to its Kelvin temperature when the volume remains constant. This means that as the temperature of the gas increases, the pressure also increases, and vice versa. This law is based on the observation that as the temperature of a gas increases, the average kinetic energy of its particles increases, leading to more frequent and forceful collisions with the walls of the container, resulting in an increase in pressure.

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80. A sample of carbon dioxide occupies a 2.54 dm3 container at STP. What is the volume of the gas at a pressure of 150.0 kPa and a temperature of 26.0°C? 

Explanation

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81. The equation for the combined gas law can be used instead of which of the following equations?

Explanation

The combined gas law is a mathematical equation that combines Boyle's law, Charles's law, and Gay-Lussac's law. It allows us to calculate the relationship between pressure, volume, and temperature of a gas when at a constant amount. Therefore, the combined gas law can be used instead of any of these individual laws when we want to analyze the behavior of a gas under different conditions.

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82. A colligative property of solutions  

Explanation

Osmotic pressure is a colligative property of solutions. It is the pressure required to prevent the flow of water molecules across a semipermeable membrane due to osmosis. Osmosis is the movement of solvent molecules (in this case, water) from an area of lower solute concentration (pure solvent side) to an area of higher solute concentration (solution side) through a semipermeable membrane. In this process, the solute particles (sugar molecules) cannot pass through the membrane, so water moves to balance the concentration on both sides. The osmotic pressure is directly related to the concentration of solute particles and can be used to determine the concentration of a solution.

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83. What information is NOT given by the coefficients in a balanced chemical equation?

Explanation

The coefficients in a balanced chemical equation represent the mole ratios of reactants and products, which means they provide information about the relative number of moles of each substance involved in the reaction. However, they do not directly give information about the mass ratios of reactants and products. This is because the molar mass of each substance must be taken into account to calculate the mass ratios. Therefore, the mass ratios cannot be determined solely from the coefficients in the balanced equation.

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84. If the pressure of a gas is measured in mm Hg, then the value of the gas constant, R, is ____________________.

Explanation

The value of the gas constant, R, is 62.4 when the pressure of a gas is measured in mm Hg.

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85. What happens to the pressure of the gas in an inflated expandable balloon if the temperature is increased?

Explanation

When the temperature of a gas inside an inflated expandable balloon is increased, the average kinetic energy of the gas molecules also increases. As a result, the gas molecules move faster and collide with the walls of the balloon more frequently and with greater force. This increased frequency and force of collisions exert a greater pressure on the walls of the balloon. However, since the balloon is expandable, it can stretch and accommodate the increased pressure. Therefore, the pressure inside the balloon remains the same when the temperature is increased.

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86. The amount of additional pressure caused by water molecules moving into a solution 

Explanation

Osmotic pressure refers to the amount of additional pressure exerted by water molecules as they move into a solution through a semipermeable membrane, in order to equalize the concentration of solute on both sides of the membrane. This process is known as osmosis. Osmotic pressure is dependent on the concentration of solute particles in the solution, with higher concentrations resulting in higher osmotic pressure.

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87. A steel tank with a volume of 9.583 L contains N2 gas under a pressure of 4.972 atm at 31.8 °C. Calculate the number of moles of N2 in the tank

Explanation

The ideal gas law, PV = nRT, can be used to solve this problem. First, convert the temperature to Kelvin by adding 273.15 to 31.8 °C, giving 304.95 K. Next, convert the pressure to Pascals by multiplying 4.972 atm by 101325 Pa/atm, giving 504238.9 Pa. Rearranging the ideal gas law equation to solve for n, we have n = PV / RT. Plugging in the values, we get n = (504238.9 Pa)(9.583 L) / (8.314 J/(mol K))(304.95 K). Simplifying this expression gives us n = 1.90 mol. Therefore, the number of moles of N2 in the tank is 1.90 mol.

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88. The volume of a sample of helium is 4.50 mL at 20.0°C and 203.0 kPa. What will its volume be at 10.0°C and 203.0 kPa? 

Explanation

As the pressure remains constant at 203.0 kPa, we can use the combined gas law to solve this problem. The combined gas law equation is P1V1/T1 = P2V2/T2, where P1 and P2 are the initial and final pressures, V1 and V2 are the initial and final volumes, and T1 and T2 are the initial and final temperatures. Since the pressure remains constant, we can simplify the equation to V1/T1 = V2/T2. Plugging in the given values, we have (4.50 mL)/(20.0°C) = V2/(10.0°C). Solving for V2, we find that V2 = (4.50 mL)(10.0°C)/(20.0°C) = 4.34 mL. Therefore, the volume will be 4.34 mL at 10.0°C.

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89. The diffusion of the solvent particles across the semipermeable membrane from the area of higher solvent concentration to the area of lower solvent concentration 

Explanation

Osmosis refers to the movement of solvent particles, typically water molecules, across a semipermeable membrane from an area of higher solvent concentration to an area of lower solvent concentration. This process occurs in order to equalize the concentration of solute particles on both sides of the membrane. In osmosis, the solvent molecules pass through the membrane, while the solute particles, such as sugar molecules, are unable to cross the membrane. Therefore, the correct answer is osmosis.

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90. A measure of how much solute is dissolved in a specific amount of solvent or solution 

Explanation

Concentration is a measure of how much solute is dissolved in a specific amount of solvent or solution. It is a way of expressing the amount of solute present in a given volume or mass of solution. It is typically measured in moles per liter (M), grams per liter (g/L), or other similar units. Concentration is an important factor in many chemical and biological processes, as it affects the rate and extent of reactions, as well as the properties and behavior of solutions.

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91. How many moles of helium gas are contained in a 4.0-L flask at STP?

Explanation

At STP (Standard Temperature and Pressure), one mole of any gas occupies a volume of 22.4 liters. Therefore, to find the number of moles of helium gas in a 4.0-L flask at STP, we can use the ratio of volumes. Since 4.0 L is less than 22.4 L, we can infer that there is less than one mole of helium gas in the flask. The closest option to a fraction of a mole is 0.17 mol, which is the correct answer.

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92. The statement that the solubility of a gas in a liquid is directly proportional to the pressure of the gas above the liquid

Explanation

Henry's law states that the solubility of a gas in a liquid is directly proportional to the pressure of the gas above the liquid. This means that as the pressure of the gas increases, more gas molecules will dissolve in the liquid. Conversely, if the pressure decreases, the solubility of the gas will also decrease. Henry's law is important in understanding gas-liquid equilibria and is commonly used to explain phenomena such as the carbonation of beverages or the release of dissolved gases from water when it is heated.

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Air is a(n)  _______________ of oxygen gas dissolved in...
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The side that exerts osmotic pressure 
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The overall energy change that occurs when a solution forms
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Air is a(n)  ____________ of oxygen gas dissolved in nitrogengas....
According to Gay-Lussac's law: 
Air is a(n)  ____________ of oxygen gas dissolved in nitrogengas....
In a hospital, oxygen is administered to patients at 3.0 atm in a...
Which of the following statements explains the solubility of ionic...
The type of solution formed by creek water after heavy rain is called...
The physical behavior of an ideal gas can be expressed in terms of the...
R represents the relationship among pressure, volume, temperature, and...
The pressure of a given mass of gas varies directly with the kelvin...
A sample of carbon dioxide occupies a 2.54 dm3 container at STP. What...
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A colligative property of solutions  
What information is NOT given by the coefficients in a balanced...
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A steel tank with a volume of 9.583 L contains N2 gas under a pressure...
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