Alkenes And Reactions Quiz

The reaction of an alkene with O3 (ozone) followed by Zn/H3O+ (reduction) leads to the cleavage of the double bond and the formation of carbonyl compounds where each double bonded carbon is double bonded to an oxygen atom.

When an alkene is reacted with KMnO4 and H3O+, the product depends on the number of hydrogen atoms bonded to the carbon atoms involved in the reaction. Alkenes can undergo oxidative cleavage with KMnO4 and H3O+ to form different products such as aldehydes, carboxylic acids, or carbon dioxide based on the number of hydrogen atoms present.

Periodic acid (HIO4) cleaves vicinal diols to form two aldehyde or ketone groups, each containing a C=O bond. This reaction is commonly used for oxidative cleavage of diols.

The reaction of an alkene with HCl, HBr, or HI follows the Markovnikov rule, where the X (halide) group adds to the carbon with more hydrogen atoms, and the H adds to the other carbon. This results in the formation of a product with X on one carbon and H on the other carbon.

When an alkene reacts with Cl2 or Br2, anti addition occurs leading to one X on each carbon. This is due to the nature of the mechanism involved in the reaction process.

When an alkene reacts with X2 and H2O, it undergoes Markovnikov addition, where the X attaches to one carbon and the OH attaches to the other carbon in an anti fashion. This is a common reaction mechanism in organic chemistry.

The reaction described involves the oxymercuration-demercuration of an alkene. The mercury catalyst (Hg(OAc)2) adds an OH group to the more substituted carbon, following Markovnikov's rule. The addition of NaBH4 then reduces the mercury and removes it, resulting in an alkene with the OH group on one carbon and an H atom on the other carbon.

The reaction between an alkene and BH3, THF, H2O2, OH- results in a non-Markovnikov addition with OH on one carbon and H on the other carbon due to the syn addition mechanism.

When alkene reacts with CHCl3 and KOH, it undergoes a halogenation reaction resulting in the formation of cyclopropane with two Cl atoms attached.

The reaction involving alkene with CH2I2, Zn(Cu), and ether results in the formation of cyclopropane due to the Simmons-Smith reaction, which involves the generation of a carbene intermediate that then reacts with the alkene to form a cyclopropane ring.

When alkene reacts with H2 in the presence of Pd/C or PtO2, it results in syn addition of hydrogen atoms leading to the formation of an alkane.

When an alkene reacts with a peroxyacid, a syn addition occurs where an epoxide is produced with two carbon atoms attached to one oxygen atom. This reaction does not result in anti addition or rearrangement. It is important to understand the specific reactivity of peroxyacid with alkenes to predict the correct product formation.

When an epoxide reacts with H3O+, the nucleophile adds to the least sterically hindered carbon, resulting in the formation of an anti product with one OH group on each carbon. This differs from the syn product where both OH groups would be on the same carbon or cis product where both OH groups would be on different carbons.