1.
Electrical fires cannot be safely put out by dousing them with water. However, fire extinguishers spray solid carbon dioxide on the firework very effectively. This method works because of carbon dioxide:
Correct Answer
A. Displaces the oxygen.
Explanation
Carbon dioxide displaces oxygen, which is necessary for combustion to occur. By removing oxygen from the fire, carbon dioxide effectively extinguishes it.
2.
To advance to the level of a theory, a hypothesis should be:
Correct Answer
D. Repeatedly confirmed by experimentation.
Explanation
A hypothesis becomes a theory when it is repeatedly confirmed by experimentation. This means that the hypothesis has been tested multiple times, and the results consistently support it. Repeated confirmation through experimentation provides stronger evidence and increases confidence in the hypothesis, leading to its advancement as a theory. It is important to note that a hypothesis does not need to be obviously accepted by most people or fully functional experiment, nor does it need to be in alignment with past theories, in order to become a theory.
3.
When a metal is heated in a flame, the flame has a distinctive color. This information was eventually extended to the study of stars because:
Correct Answer
A. The color spectra of stars indicate which elements are present.
Explanation
When a metal is heated in a flame, it emits light of specific wavelengths, creating a distinctive color. This phenomenon is due to the excitation and subsequent relaxation of electrons in the metal atoms. Similarly, the color spectra of stars can be observed and analyzed to determine the elements present in their atmospheres. Each element emits light at specific wavelengths, resulting in characteristic spectral lines. By comparing the observed spectra of stars with known spectra of elements, scientists can identify the elements present in stars. Therefore, the color spectra of stars provide valuable information about the composition of stars.
4.
Which of the following ordered pairs of elements shows an increase in atomic number but a decrease in average atomic mass?
Correct Answer
B. Co to Ni
Explanation
The correct answer is Co to Ni. This is because as we move from cobalt (Co) to nickel (Ni) in the periodic table, the atomic number increases, indicating an increase in the number of protons in the nucleus. However, the average atomic mass decreases because the increase in atomic number is not accompanied by a significant increase in the number of neutrons.
5.
Iodine would have chemical properties most like:
Correct Answer
C. Chlorine (Cl)
Explanation
Iodine would have chemical properties most like chlorine (Cl) because they both belong to the same group in the periodic table, Group 17 or the halogens. Halogens share similar chemical properties due to their similar electronic configurations and their tendency to gain one electron to achieve a stable octet. Both iodine and chlorine are nonmetals and highly reactive, forming compounds with other elements. They also have similar physical properties, such as being diatomic molecules in their elemental form and having similar boiling points.
6.
The chart above shows the relationship between the first ionization energy and the increase in atomic number. The letter on the chart for the alkali family of elements is:
Correct Answer
A. W
Explanation
The first ionization energy is the energy required to remove the outermost electron from an atom. In general, the first ionization energy decreases as you move down a group in the periodic table, because the outermost electron is further from the nucleus and therefore easier to remove. The alkali family of elements is located in Group 1 of the periodic table, which includes elements like lithium, sodium, and potassium. Based on this information, we can conclude that the letter on the chart for the alkali family of elements is W.
7.
Which of the following atoms has six valence electrons?
Correct Answer
C. Sulfur (S)
Explanation
Sulfur (S) has six valence electrons. The valence electrons are the outermost electrons in an atom, and they are responsible for the atom's chemical behavior. In the case of sulfur, it is located in Group 16 of the periodic table, which means it has six valence electrons. Magnesium (Mg) has two valence electrons, silicon (Si) has four valence electrons, and argon (Ar) has eight valence electrons.
8.
Which statement best describes the density of an atom’s nucleus?
Correct Answer
D. The nucleus occupies very little of the atom’s volume but contains most of its mass.
Explanation
The correct answer is that the nucleus occupies very little of the atom's volume but contains most of its mass. This is because the nucleus is a small, dense region at the center of the atom where most of its mass is concentrated. The rest of the atom's volume is occupied by the electron cloud, which is much larger but contains very little mass compared to the nucleus.
9.
A 2-cm-thick piece of cardboard placed over a radiation source would be most effective in protecting against which type of radiation?
Correct Answer
A. AlpHa
Explanation
A 2-cm-thick piece of cardboard would be most effective in protecting against alpha radiation. Alpha particles are larger and have a positive charge, so they have a limited range and can be stopped by a sheet of paper or a few centimeters of air. Cardboard, being thicker than paper, would provide an additional barrier against alpha particles, effectively protecting against this type of radiation.
10.
The reason salt crystals, such as KCl, hold together so well is that the cations are strongly attracted to:
Correct Answer
D. Neighboring anions.
Explanation
Salt crystals, such as KCl, hold together so well because the cations are strongly attracted to neighboring anions. In an ionic compound like salt, the cations (positively charged ions) and anions (negatively charged ions) are held together by electrostatic forces. The positive charge of the cations is attracted to the negative charge of the anions, creating a strong bond between them. This attraction between opposite charges is what allows the salt crystals to maintain their structure and hold together tightly.
11.
Which of the following elements has the same Lewis dot structure as silicon?
Correct Answer
A. Germanium (Ge)
Explanation
Germanium (Ge) has the same Lewis dot structure as silicon because they both belong to Group 14 of the periodic table. Group 14 elements have four valence electrons, which are represented by four dots around the element symbol in the Lewis dot structure. Silicon and germanium are both semiconductors and share similar chemical properties due to their similar electron configurations. Therefore, germanium has the same Lewis dot structure as silicon.
12.
Which substance is made up of many monomers joined together in long chains?
Correct Answer
B. Protein
Explanation
Proteins are substances made up of many monomers joined together in long chains. Monomers are small molecules that can bond together to form larger molecules called polymers. In the case of proteins, the monomers are amino acids, which are linked together by peptide bonds to form long chains. These chains can then fold and interact with each other to create complex three-dimensional structures, giving proteins their diverse functions in the body. Salt, ethanol, and propane are not composed of monomers joined together in long chains, so they are not the correct answer.
13.
Proteins are large macromolecules composed of thousands of subunits. The structure of the protein depends on the sequence of:
Correct Answer
C. Amino acids
Explanation
Proteins are composed of thousands of subunits called amino acids. These amino acids are linked together in a specific sequence to form the structure of the protein. Each amino acid has a unique side chain, and the sequence of these side chains determines the overall structure and function of the protein. Lipids, monosaccharides, and nucleosides are not involved in the formation of protein structures, making amino acids the correct answer.
14.
The volume of 400 mL of chlorine gas at 400 mm Hg is decreased to 200 mL at a constant temperature. What is the new gas pressure?
Correct Answer
C. 800mm Hg
Explanation
When the volume of a gas is decreased while keeping the temperature constant, according to Boyle's Law, the pressure of the gas increases. Therefore, when the volume of the chlorine gas is halved from 400 mL to 200 mL, the gas pressure doubles. Since the initial pressure is 400 mm Hg, the new gas pressure would be 800 mm Hg.
15.
Standard temperature and pressure (STP) are defined as:
Correct Answer
A. 0 ºC and 1.0 atm pressure.
Explanation
Standard temperature and pressure (STP) are defined as 0 ºC and 1.0 atm pressure. This means that under standard conditions, the temperature is 0 degrees Celsius and the pressure is 1.0 atmosphere. STP is commonly used as a reference point for comparing and measuring the properties of gases.
16.
What is the equivalent of 423 kelvin in degrees Celsius?
Correct Answer
C. 150 ºC
Explanation
To convert Kelvin to Celsius, you need to subtract 273. So, 423 Kelvin minus 273 equals 150 degrees Celsius.
17.
If the attractive forces among solid particles are less than the attractive forces between the solid and a liquid, the solid will:
Correct Answer
D. Dissolve as particles are pulled away from the crystal lattice by the liquid molecules.
Explanation
When the attractive forces among solid particles are less than the attractive forces between the solid and a liquid, the solid will dissolve as particles are pulled away from the crystal lattice by the liquid molecules. This is because the attractive forces between the solid and the liquid are stronger than the attractive forces holding the solid particles together in the crystal lattice. As a result, the liquid molecules are able to overcome the forces within the crystal lattice and pull the solid particles away, causing them to dissolve in the liquid.
18.
If the solubility of NaCl at 25 ºC is 36.2 g/100 g H2O, what mass of NaCl can be dissolved in 50.0 g of H2O?
Correct Answer
A. 18.1 g
Explanation
The solubility of NaCl at 25 °C is given as 36.2 g/100 g H2O. This means that for every 100 g of water, 36.2 g of NaCl can be dissolved. To find the mass of NaCl that can be dissolved in 50.0 g of water, we can set up a proportion. Since 100 g of water can dissolve 36.2 g of NaCl, then 50.0 g of water can dissolve (50.0 g/100 g) * 36.2 g = 18.1 g of NaCl. Therefore, the correct answer is 18.1 g.
19.
How many moles of HNO3 are needed to prepare 5.0 liters of a 2.0 M solution of HNO3?
Correct Answer
C. 10
Explanation
To calculate the number of moles of HNO3 needed, we can use the formula: moles = concentration x volume. In this case, the concentration is given as 2.0 M and the volume is given as 5.0 liters. By multiplying these two values together, we get 10 moles of HNO3. Therefore, 10 moles of HNO3 are needed to prepare the 5.0 liters of a 2.0 M solution of HNO3.
20.
The random molecular motion of a substance is greatest when the substance is
Correct Answer
D. A gas
Explanation
The random molecular motion of a substance is greatest when the substance is a gas because the gas particles have more kinetic energy compared to liquids or solids. In a gas, the particles are not tightly packed and have more freedom to move around in all directions. This leads to a higher level of random motion and faster movement of particles. In liquids, the particles are closer together and have less freedom of movement, while in solids, the particles are tightly packed and have the least amount of random motion.
21.
The boiling point of liquid nitrogen is 77 kelvin. It is observed that ice forms at the opening of a container of liquid nitrogen. The best explanation for this observation is:
Correct Answer
D. The water vapor in the air over the opening of the liquid nitrogen freezes out.
Explanation
The best explanation for the observation is that the water vapor in the air over the opening of the liquid nitrogen freezes out. As liquid nitrogen boils, it releases a large amount of cold vapor. This vapor cools down the surrounding air, causing the water vapor present in the air to condense and freeze, forming ice at the opening of the container.
22.
The specific heat of copper is about 0.4 joules/ gram ºC. How much heat is needed to change the temperature of a 30-gram sample of copper from 20.0 ºC to 60.0 ºC?
Correct Answer
C. 480 J
Explanation
The specific heat of copper is given as 0.4 joules/gram °C. To calculate the heat needed to change the temperature of the copper sample, we can use the formula: heat = mass x specific heat x change in temperature. In this case, the mass of the copper sample is 30 grams, the specific heat is 0.4 joules/gram °C, and the change in temperature is 60.0 °C - 20.0 °C = 40.0 °C. Plugging these values into the formula, we get: heat = 30 grams x 0.4 joules/gram °C x 40.0 °C = 480 J. Therefore, the correct answer is 480 J.
23.
Equal volumes of 1 molar hydrochloric acid (HCl) and 1 molar sodium hydroxide base (NaOH) are mixed. After mixing, the solution will be:
Correct Answer
C. Nearly neutral
Explanation
When equal volumes of 1 molar hydrochloric acid (HCl) and 1 molar sodium hydroxide base (NaOH) are mixed, they undergo a neutralization reaction. This reaction results in the formation of water and a salt, sodium chloride (NaCl). Since the concentration of both the acid and base is the same, and they react completely, the resulting solution will have an equal number of H+ and OH- ions, making it nearly neutral.
24.
A catalyst can speed up the rate of a given chemical reaction by:
Correct Answer
B. Lowering the activation energy required for the reaction to occur.
Explanation
A catalyst can speed up the rate of a chemical reaction by lowering the activation energy required for the reaction to occur. Activation energy is the energy barrier that must be overcome for a reaction to proceed. By lowering this barrier, the catalyst allows the reaction to occur more easily and at a faster rate. The equilibrium constant, temperature, and pressure do not directly affect the activation energy, so they are not the correct answer.
25.
When a reaction is at equilibrium and more reactant is added, which of the following changes is the immediate result?
Correct Answer
B. The forward reaction rate increases.
Explanation
When a reaction is at equilibrium, it means that the forward and reverse reaction rates are equal. Adding more reactant to the system disrupts this balance and shifts the equilibrium towards the products. In order to restore the equilibrium, the forward reaction rate increases to consume the additional reactant and produce more products. The reverse reaction rate remains the same because it is not affected by the addition of reactant.
26.
In which of the following reactions involving gases would the forward reaction be favored by an increase in pressure?
Correct Answer
A. A + B AB
Explanation
Increasing the pressure in a reaction involving gases would favor the forward reaction if the total number of moles of gas on the product side is greater than the total number of moles of gas on the reactant side. In the given reaction A + B AB, the total number of moles of gas on the product side is greater than the total number of moles of gas on the reactant side (1 vs 2), so increasing the pressure would favor the forward reaction.
27.
C3H8 + O2 --> CO2 + H2O This chemical equation represents the combustion of propane. When correctly balanced, the coefficient for water is
Correct Answer
B. 4
Explanation
The balanced chemical equation for the combustion of propane is C3H8 + 5O2 -> 3CO2 + 4H2O. This means that for every 3 molecules of carbon dioxide produced, 4 molecules of water are produced. Therefore, the coefficient for water in the equation is 4.
28.
How many moles of carbon-12 is contained in exactly 6 grams of carbon-12?
Correct Answer
A. 0.5 mole
Explanation
The question is asking for the number of moles of carbon-12 in 6 grams of carbon-12. To find the number of moles, we need to divide the given mass by the molar mass of carbon-12. The molar mass of carbon-12 is 12 grams/mol. So, 6 grams of carbon-12 is equal to 6/12 = 0.5 moles.
29.
How many moles of CH4 are contained in 96.0 grams of CH4?
Correct Answer
B. 6.00 moles
Explanation
The molar mass of CH4 (methane) is 16.04 g/mol. To find the number of moles in 96.0 grams of CH4, we divide the given mass by the molar mass: 96.0 g / 16.04 g/mol = 5.98 mol. Since moles cannot be fractional, we round this to the nearest whole number, which is 6.00 moles. Therefore, there are 6.00 moles of CH4 in 96.0 grams of CH4.