There are two options for this entry: you can either use a debit card meant for stationary, or you can use a credit card from a bank meant for general business expenses. Either way, the purchase of stationary will most likely have been approved by higher ups before it’s made, and there will most likely be a specific direction for the funds that will be used for this purchase. It all depends on the specific company that is purchasing the stationary.
This may mean that employees have to pay out of pocket and be reimbursed, or it could mean that there’s a general bank account meant for ordering this kind of thing. That will also influence what kind of stationary is purchased, but that’s an answer for a different question.