Change percent to grams: 37.69 g of Na and 62.31 g of Fluorine.
Empirical formula is the simplest whole number ratio of moles.
Change grams to moles (divide by molar mass)
Na: 37.69 / 22.99 g = 1.639 moles
F : 62.31 g/19.00 g = 3.279 moles
Divide each by 1.639: Na 1 and F 2 = NaF2