Analytical Techniques CHEM 3140

Analytical technique terms

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Quantitative analysis
Measurement of the quantities of particular constituents present in a substance.
Qualitative analysis
Identification of the constituents present in a substance.
Random error
Random errors are errors in measurement that lead to measured values being inconsistent when repeated measures of a constant attribute or quantity are taken.
Standard deviation
The square root of the variance
Relative standard deviation
The deviation with respect to the value deviated from (usually a percent)
Confidence interval
A range of values so defined that there is a specified probability that the value of a parameter lies within it
Calibration Sensitivity
How sensitive the instrument is depends on how steep the calibration slope is
Analytical sensitivity
How sensitive the instrument is depends on how precise the results are
Limit of detection
The lowest quantity of a substance that can be distinguished from the absence of that substance (a blank value) within a stated confidence limit
Limit of quantification
The lowest concentration at which the analyte can not only be reliably detected but at which some predefined goals for bias and imprecision are met.
Dynamic range
The range between LOQ and LOL
External standard calibration
Using a set of standards and a calibration curve to determine the amount of analyte in a separate sample
Internal standard calibration
A chemical substance that is added in a constant amount to samples, the blank and calibration standards
Standard addition
Several solutions containing the same amount of unknown, but different amounts of standard.
Ruggedness
Precision and accuracy are insensitive to environment changes