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Organich Chemistry Synthesis
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Side A ------ Side B Add a branched group ------ Tag a Br on the end that adds to ring, use AlCl3 as catalyst Add a halide -Cl ------ FeCl3 Cl-Cl Add NO2 ------ HNO3 H2SO4 Convert NO2 to NH2 ------ ZnHg & HCl or H2Pd Convert NH2 to NO2 ------ oxidize CR3COOOH Reduce something with a double bond to oxygen to a single-bond hydrocarbon ------ ZnHg & HCl or H2Pd Oxidize a hydrocarbon to contain a double bonded oxygen ------ CrO3 H2SO4 H2O Oxidize an alkyl ------ KMnO4 Total reduction (including armomaticity) ------ H2Pt at 2000psi or H2Rh Add SO3 ------ SO3 H2SO4 Remove SO3 ------ H3O+ H2O Grignard Reaction ------ Grignard reaction. This reaction adds a halomagnesium reagent (Grignard reagent) to a carbonyl to make an alcohol. Diels-Alder ------ Diels-Alder reaction. This reaction takes a diene and a dienophile to make ringed and bicyclic products. Makes 2 C-C bonds. Friedel-Crafts ------ Friedel-Crafts reactions (for aromatic rings). This reaction makes an aromatic-carbon bond. Wittig ------ The Wittig Reaction. Makes a carbon-carbon double bond starting with a carbonyl compound phosphonium ylide Cyanide addition ------ Cyanide additions to primary halides. Acetylide Reactions ------ Acetylide reactions. These reactions involve use of an acetylide (a deprotonated terminal alkyne) as a nucleophile. Typically, the acetylide is used to attack a primary halide (or a carbonyl group to make an alcohol.
Side A ------ Side B Add a branched group ------ Tag a Br on the end that adds to ring, use AlCl3 as catalyst Add a halide -Cl ------ FeCl3 Cl-Cl Add NO2 ------ HNO3 H2SO4 Convert NO2 to NH2 ------ ZnHg & HCl or H2Pd Convert NH2 to NO2 ------ oxidize CR3COOOH Reduce something with a double bond to oxygen to a single-bond hydrocarbon ------ ZnHg & HCl or H2Pd Oxidize a hydrocarbon to contain a double bonded oxygen ------ CrO3 H2SO4 H2O Oxidize an alkyl ------ KMnO4 Total reduction (including armomaticity) ------ H2Pt at 2000psi or H2Rh Add SO3 ------ SO3 H2SO4 Remove SO3 ------ H3O+ H2O Grignard Reaction ------ Grignard reaction. This reaction adds a halomagnesium reagent (Grignard reagent) to a carbonyl to make an alcohol. Diels-Alder ------ Diels-Alder reaction. This reaction takes a diene and a dienophile to make ringed and bicyclic products. Makes 2 C-C bonds. Friedel-Crafts ------ Friedel-Crafts reactions (for aromatic rings). This reaction makes an aromatic-carbon bond. Wittig ------ The Wittig Reaction. Makes a carbon-carbon double bond starting with a carbonyl compound phosphonium ylide Cyanide addition ------ Cyanide additions to primary halides. Acetylide Reactions ------ Acetylide reactions. These reactions involve use of an acetylide (a deprotonated terminal alkyne) as a nucleophile. Typically, the acetylide is used to attack a primary halide (or a carbonyl group to make an alcohol.
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