Thermodynamics

Total Flash Cards » 41
Text Size » S M L
1. 1st law of thermodynamics the total energy of the universe is constant
2. 2nd law of thermodynamics the total entropy of the universe is always incresing
3. 3rd law of thermodynamics the entropy of every pure perfectly formed crystalline substance at absolute zero is zero
4. a negative delta H is what kind of reaction? exothermic
5. a positive delta H is what kind of reaction? endothermic
6. definition of entropy measure of disorder
7. 4 rules of entropy 1. gases have greater entropy than liquids
2. liquids have greater entropy than solids
3. entropy of a system increases as temp increases
4. in a chemical reaction the side with more mols has greater entropy
8. thermochemistry the heat changes that occur during chemical reactions
9. energy the capacity for doing work or supplying heat
10. what is the energy stored in chemical bonds called? chemical potential energy
11. heat energy that transfers from one object to another becuase of a temperature difference between them.
12. calorie the quantity of heat needed to raise the temp of 1g of pure water 1 degree C
13. kilocalorie equal to 1000 calories
14. joule the SI unit of heat and energy named after the English physicist James Prescott Joule
15. how many joules in 1 calorie? 4.184 Joules
16. Heat capacity the amount of heat needed to increase the temp of an object exactly 1 degree C
17. Specific heat capacity the amount of heat it takes to raise the temp of 1g of the substance 1 degree C
18. calorimeter a device for measuring heat changes
19. enthalpy the heat content of a system at constant pressure
20. what does delta H stand for? heat of reaction or enthaply of reaction
21. Hess's law if you add two or more thermochemical equations to get the final equation, then you can also add the heat of reaction to five the final heat reaction.
22. standard heat of formation the change in enthaply that accompanies the formation of one mol of a compound from its elements with all substances in their standard states at 25 degrees C
23. free energy energy that is available to do work
24. spontaneous reactions reactions that occur naturally and that facor the formation of products at the specified conditions
25. nonspontaneous reactions reactions that do not facor the formation of products at the specified conditions
26. standard entropy the entropy of a substance in its stable state at 25 degrees C
27. Gibb's free energy the maximum amount of energy that can be coupled to another provess to do useful work
28.
CaCO3(s) + 176kJ ----> CaO(s) + CO2(g)
a. caculate the energy required to decompose 5.20 mol of CaCO3
b. how many kcal are required?

a. 915 kJ
b. 219 kcal
29.
SO3 + H2O -----> H2SO4 + 129.6 kJ
how much heat in kJ and kcal is released when 583 grams of SO3 reacts with water?
a.
30.
2CO2 + 43.9 kJ ----> 2CO + O2
how many molecules of CO2 can be decomposed by the addition of 22.2 kJ of heat?
6.09x10^23 molecules
31.
2C2H6(g) + 7O2(g) ---> 4CO2(g) + 6H2O(l)
calculate delta H, delta S, and delta G

a. H= -3119.6 kJ/mol
b. S= -620.7 J/kmol
c. G= -2934.57 kJ/mol
32.
2NO2(g) ---> N2O4(g)
calculate delta H,S and G
33.
2Fe + 3CO2 + 26.3kJ ---> Fe2O3 + 3CO
a. calculate kJ for 7.3 mols of Fe
b. is this a positive or negative enthalpy change?

a. 96 kJ
b. positive
34.
2Mg + O2 ----> 2MgO + 288kcal
a. calculate kcal for 0.12 mols of Mg
b. calculate kJ

a. -17kcal
b. -71kJ
35.
C2H4 + 3O2 ----> 2CO2 + 2H2O + 1.39x10^3
calculate the heat for 1.87g of C2H4
-92.7kJ
36.
I2(s) ----> I2(g)
calculate delta H,S and G

H=62.438 kJ/mol
S=144.56 J/kmol
G=19.327 kJ/mol
37.
3CO(g) + Fe2O3(s) ----> 2Fe(s) + 3CO2(g)
calculate delta H,S and G

H= -24.7 kJ/mol
S= 16.36 J/kmol
G= -29.4 kJ/mol
38.
2NO2(g) ---> 2NO(g) + 2H2O(g)
calculate delta H,S and G

H= -369.5 kJ/mol
S= 319.05 J/kmol
39.
2NO(g) + O2(g) ----> 2NO2(g)
calculate delta H,S and G

H= -144.1 kJ/mol
S= -146.54 J/kmol
40.
2HF(g) ---> H2(g) + F2(g) at 1030. C
calculate delta H,S and G

H= 542.2 kJ/mol
S= -14.10 J/kmol
G= 560.6 kJ/mol
41.
NaOH(s) + HCl(aq) ---> NaCl(aq) + H2O(l)
at 85.0 C
calculate delta H,S and G

H= 100.33 kJ/mol
S= 64.4 J/kmol
G= -123.4 kJ/mol